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Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate

[Image: see text] Electrophilic high-valent metal ions are potent intermediates for the catalytic functionalization of methane, but in many cases, their high redox potentials make these intermediates difficult or impossible to access using mild stoichiometric oxidants derived from O(2). Herein, we e...

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Veröffentlicht in:ACS Cent Sci
Hauptverfasser: O’Reilly, Matthew E., Kim, R. Soyoung, Oh, Seokjoon, Surendranath, Yogesh
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2017
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5704285/
https://ncbi.nlm.nih.gov/pubmed/29202019
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.7b00342
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