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Selective Monofunctionalization Enabled by Reaction History-Dependent Communication in Catalytic Rotaxanes

Selective monofunctionalization of substrates with distant, yet equally-reactive functional groups is difficult to achieve, as it requires the second functional group to selectively modulate its reactivity once the first functional group has reacted. We now show that mechanically-interlocked catalyt...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Rajappan, Sinu C., McCarthy, Dillon R., Campbell, Joseph P., Ferrell, Jonathon B., Sharafi, Mona, Ambrozaite, Ona, Li, Jianing, Schneebeli, Severin T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7719090/
https://ncbi.nlm.nih.gov/pubmed/32525593
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006305
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