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Biomimetic Platinum-Promoted Polyene Polycyclizations – Influence of Alkene Substitution and Pre-Cyclization Conformations
Results of kinetic experiments and quantum chemical computations on a series of platinum-promoted polycyclization reactions are described. Analysis of these results reveal a reactivity model that reaches beyond the energetics of the cascade itself, incorporating an ensemble of pre-cyclization confor...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5699452/ https://ncbi.nlm.nih.gov/pubmed/28719198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05381 |
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