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The Generation of Dehydroalanine Residues in Protonated Polypeptides: Ion/ion Reactions for Introducing Selective Cleavages

We examine a gas-phase approach for converting a sub-set of amino acid residues in polypeptide cations to dehydroalanine (Dha). Subsequent activation of the modified polypeptide ions gives rise to specific cleavage N-terminal to the Dha residue. This process allows for the incorporation of selective...

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Detalhes bibliográficos
Publicado no:J Am Soc Mass Spectrom
Main Authors: Peng, Zhou, Bu, Jiexun, McLuckey, Scott A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5681889/
https://ncbi.nlm.nih.gov/pubmed/28497355
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-017-1672-5
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