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Laboratory-scale photoredox catalysis using hydrated electrons sustainably generated with a single green laser

The ruthenium-tris-bipyridyl dication as catalyst combined with the ascorbate dianion as bioavailable sacrificial donor provides the first regenerative source of hydrated electrons for chemical syntheses on millimolar scales. This electron generator is operated simply by illumination with a frequenc...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Naumann, Robert, Kerzig, Christoph, Goez, Martin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5676201/
https://ncbi.nlm.nih.gov/pubmed/29163905
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03514d
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