Hydrophilic sulfonated bis-1,2,4-triazine ligands are highly effective reagents for separating actinides(iii) from lanthanides(iii) via selective formation of aqueous actinide complexes

We report the first examples of hydrophilic 6,6′-bis(1,2,4-triazin-3-yl)-2,2′-bipyridine (BTBP) and 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) ligands, and their applications as actinide(iii) selective aqueous complexing agents. The combination of a hydrophobic diamide ligand in the or...

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Detalles Bibliográficos
Publicado en:Chem Sci
Autores principales: Lewis, Frank W., Harwood, Laurence M., Hudson, Michael J., Geist, Andreas, Kozhevnikov, Valery N., Distler, Petr, John, Jan
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5667576/
https://ncbi.nlm.nih.gov/pubmed/29142716
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01328c
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