Replacing Nitrogen by Sulfur: From Structurally Disordered Eumelanins to Regioregular Thiomelanin Polymers

The oxidative polymerization of 5,6-dihydroxybenzothiophene (DHBT), the sulfur analog of the key eumelanin building block 5,6-dihydroxyindole (DHI), was investigated to probe the role of nitrogen in eumelanin build-up and properties. Unlike DHI, which gives a typical black insoluble eumelanin polyme...

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Detalhes bibliográficos
Publicado no:Int J Mol Sci
Main Authors: Iacomino, Mariagrazia, Mancebo-Aracil, Juan, Guardingo, Mireia, Martín, Raquel, D’Errico, Gerardino, Perfetti, Marco, Manini, Paola, Crescenzi, Orlando, Busqué, Félix, Napolitano, Alessandra, d’Ischia, Marco, Sedó, Josep, Ruiz-Molina, Daniel
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2017
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5666850/
https://ncbi.nlm.nih.gov/pubmed/29039817
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms18102169
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