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Eumelanin broadband absorption develops from aggregation-modulated chromophore interactions under structural and redox control

Eumelanins, the chief photoprotective pigments in man and mammals, owe their black color to an unusual broadband absorption spectrum whose origin is still a conundrum. Excitonic effects from the interplay of geometric order and disorder in 5,6-dihydroxyindole (DHI)-based oligomeric/polymeric structu...

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Detalhes bibliográficos
Publicado no:Sci Rep
Main Authors: Micillo, Raffaella, Panzella, Lucia, Iacomino, Mariagrazia, Prampolini, Giacomo, Cacelli, Ivo, Ferretti, Alessandro, Crescenzi, Orlando, Koike, Kenzo, Napolitano, Alessandra, d’Ischia, Marco
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5288692/
https://ncbi.nlm.nih.gov/pubmed/28150707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep41532
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