Mild, Redox-Neutral Formylation of Aryl Chlorides via Photocatalytic Generation of Chlorine Radicals

We report a redox-neutral formylation of aryl chlorides that proceeds through selective 2-functionalization of 1,3-dioxolane via nickel and photoredox catalysis. This scalable, benchtop approach provides a distinct advantage over traditional reductive carbonylation in that no carbon monoxide, pressu...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Nielsen, Matthew K., Shields, Benjamin J., Liu, Junyi, Williams, Michael J., Zacuto, Michael J., Doyle, Abigail G.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2017
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5662441/
https://ncbi.nlm.nih.gov/pubmed/28471521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201702079
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