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Boronic acids facilitate rapid oxime condensations at neutral pH

We report here the discovery and development of boron-assisted oxime formation as a powerful connective reaction for chemical biology. Oximes proximal to boronic acids form in neutral aqueous buffer with rate constants of more than 10(4) M(–1) s(–1), the largest to date for any oxime condensation. B...

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書目詳細資料
發表在:Chem Sci
Main Authors: Schmidt, Pascal, Stress, Cedric, Gillingham, Dennis
格式: Artigo
語言:Inglês
出版: Royal Society of Chemistry 2015
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5656983/
https://ncbi.nlm.nih.gov/pubmed/29142692
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00921a
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