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meta‐Selective C−H Borylation of Benzylamine‐, Phenethylamine‐, and Phenylpropylamine‐Derived Amides Enabled by a Single Anionic Ligand

Selective functionalization at the meta position of arenes remains a significant challenge. In this work, we demonstrate that a single anionic bipyridine ligand bearing a remote sulfonate group enables selective iridium‐catalyzed borylation of a range of common amine‐containing aromatic molecules at...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Davis, Holly J., Genov, Georgi R., Phipps, Robert J.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5656929/
https://ncbi.nlm.nih.gov/pubmed/28877397
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708967
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