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Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine–diphosphine ligands
A new iridium catalyst containing an imine–diphosphine ligand has been developed, which showed high efficiency for the hydrogenation of CO(2) to formate (yield up to 99%, TON up to 450 000). A possible catalytic mechanism is proposed, in which the imine group of the catalyst plays a key role in the...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5655897/ https://ncbi.nlm.nih.gov/pubmed/29308169 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00248f |
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