Exceptionally long-lived light-emitting electrochemical cells: multiple intra-cation π-stacking interactions in [Ir(C^N)(2)(N^N)][PF(6)] emitters

A series of cyclometalated iridium(iii) complexes [Ir(C^N)(2)(N^N)][PF(6)] (N^N = 2,2′-bipyridine (1), 6-phenyl-2,2′-bipyridine (2), 4,4′-di-tert-butyl-2,2′-bipyridine (3), 4,4′-di-tert-butyl-6-phenyl-2,2′-bipyridine (4); HC^N = 2-(3-phenyl)phenylpyridine (HPhppy) or 2-(3,5-diphenyl)phenylpyridine (...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Bünzli, Andreas M., Constable, Edwin C., Housecroft, Catherine E., Prescimone, Alessandro, Zampese, Jennifer A., Longo, Giulia, Gil-Escrig, Lidón, Pertegás, Antonio, Ortí, Enrique, Bolink, Henk J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5654370/
https://ncbi.nlm.nih.gov/pubmed/29142683
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03942d
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