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Positional Isomerism in the N^N Ligand: How Much Difference Does a Methyl Group Make in [Cu(P^P)(N^N)](+) Complexes?

The synthesis and structural characterization of 5,6′-dimethyl-2,2′-bipyridine (5,6′-Me(2)bpy) are reported, along with the preparations and characterizations of [Cu(POP)(5,6′-Me(2)bpy)][PF(6)] and [Cu(xantphos)(5,6′-Me(2)bpy)][PF(6)] (POP = bis(2-(diphenylphosphanyl)phenyl)ether, xantphos = 4,5-bis...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Brunner, Fabian, Prescimone, Alessandro, Constable, Edwin C., Housecroft, Catherine E.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7356218/
https://ncbi.nlm.nih.gov/pubmed/32549279
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25122760
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