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Nickel Catalyzed Cross-Coupling of Vinyl-Dioxanones to Form Enantiomerically Enriched Cyclopropanes
Under the conditions of nickel(0) catalysis, enantiomerically enriched vinyl-dioxanones engage boroxines or B(2)(pin)(2) in stereospecific cross-coupling to form diverse tetrasubstituted cyclopropanes bearing all-carbon quaternary stereocenters. The collective data corroborate a mechanism involving...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5651680/ https://ncbi.nlm.nih.gov/pubmed/28489371 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03371 |
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