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Protonation of carboxyl groups in EuDOTA-tetraamide complexes results in catalytic prototropic exchange and quenching of the CEST signal
The CEST properties of EuDOTA-tetraamide complexes bearing pendant carboxylate and carboxyl ethyl esters were measured as a function of pH. The CEST signal from the Eu(3+)-bound water molecule decreased in intensity between pH 8.5 and 4.5 while the proton exchange rates (k(ex)) increased over this s...
Tallennettuna:
| Julkaisussa: | Philos Trans A Math Phys Eng Sci |
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| Päätekijät: | , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
The Royal Society Publishing
2017
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5647270/ https://ncbi.nlm.nih.gov/pubmed/29038382 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsta.2017.0113 |
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