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N-Heterocyclic carbene catalysed redox isomerisation of esters to functionalised benzaldehydes

N-Heterocyclic carbene catalysed redox isomerisation with reduction about the carbonyl has been developed in the transformation of trienyl esters to tetrasubstituted benzaldehydes. The reaction proceeds in good to excellent yield, and in cases that provide 2,2′-biaryls, enantioselectivity is observe...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Candish, Lisa, Levens, Alison, Lupton, David W.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5645917/
https://ncbi.nlm.nih.gov/pubmed/29308150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03726j
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