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N-Heterocyclic carbene catalysed redox isomerisation of esters to functionalised benzaldehydes

N-Heterocyclic carbene catalysed redox isomerisation with reduction about the carbonyl has been developed in the transformation of trienyl esters to tetrasubstituted benzaldehydes. The reaction proceeds in good to excellent yield, and in cases that provide 2,2′-biaryls, enantioselectivity is observe...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Candish, Lisa, Levens, Alison, Lupton, David W.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5645917/
https://ncbi.nlm.nih.gov/pubmed/29308150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03726j
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