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N-Heterocyclic carbene catalysed redox isomerisation of esters to functionalised benzaldehydes

N-Heterocyclic carbene catalysed redox isomerisation with reduction about the carbonyl has been developed in the transformation of trienyl esters to tetrasubstituted benzaldehydes. The reaction proceeds in good to excellent yield, and in cases that provide 2,2′-biaryls, enantioselectivity is observe...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Candish, Lisa, Levens, Alison, Lupton, David W.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5645917/
https://ncbi.nlm.nih.gov/pubmed/29308150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03726j
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