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Mechanistic analysis of a copper-catalyzed C–H oxidative cyclization of carboxylic acids

We recently reported that carboxylic acids can be oxidized to lactone products by potassium persulfate and catalytic copper acetate. Here, we unravel the mechanism for this C–H functionalization reaction using desorption electrospray ionization, online electrospray ionization, and tandem mass spectr...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Banerjee, Shibdas, Sathyamoorthi, Shyam, Du Bois, J., Zare, Richard N.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5642147/
https://ncbi.nlm.nih.gov/pubmed/29147527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02240a
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