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Electronic Structure of the [Cu(3)(μ-O)(3)](2+) Cluster in Mordenite Zeolite and Its Effects on the Methane to Methanol Oxidation

[Image: see text] Identifying Cu-exchanged zeolites able to activate C–H bonds and selectively convert methane to methanol is a challenge in the field of biomimetic heterogeneous catalysis. Recent experiments point to the importance of trinuclear [Cu(3)(μ-O)(3)](2+) complexes inside the micropores o...

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Veröffentlicht in:J Phys Chem C Nanomater Interfaces
Hauptverfasser: Vogiatzis, Konstantinos D., Li, Guanna, Hensen, Emiel J. M., Gagliardi, Laura, Pidko, Evgeny A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2017
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5641944/
https://ncbi.nlm.nih.gov/pubmed/29051794
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcc.7b08714
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