Synthesis of 4H‐Benzo[e][1,3]oxazin‐4‐ones by a Carbonylation–Cyclization Domino Reaction of ortho‐Halophenols and Cyanamide

A mild and convenient one‐step preparation of 4H‐1,3‐benzoxazin‐4‐ones by a domino carbonylation–cyclization process is developed. Readily available ortho‐iodophenols are subjected to palladium‐catalyzed carbonylative coupling with Mo(CO)(6) and cyanamide, followed by a spontaneous, intramolecular c...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:ChemistryOpen
Hlavní autoři: Åkerbladh, Linda, Chow, Shiao Y., Odell, Luke R., Larhed, Mats
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2017
Témata:
Full Papers
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5641915/
https://ncbi.nlm.nih.gov/pubmed/29046856
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201700130
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!

Podobné jednotky