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A New Look at the Role of Thiolate Ligation in Cytochrome P450
Protonated ferryl (or iron(IV)hydroxide) intermediates have been characterized in several thiolate-ligated heme proteins that are known to catalyze C-H bond activation. The basicity of the ferryl intermediates in these species has been proposed to play a critical role in facilitating this chemistry,...
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| Published in: | J Biol Inorg Chem |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2017
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5640440/ https://ncbi.nlm.nih.gov/pubmed/28091754 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-016-1430-3 |
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