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Methylene C(sp(3))–H Arylation of Aliphatic Ketones Using a Transient Directing Group
Palladium-catalyzed methylene β-C(sp(3))–H arylation of aliphatic ketones using a transient directing group is developed. The use of α-benzyl β-alanine directing group that forms a six-membered chelation with palladium is crucial for promoting the methylene C(sp(3))–H bond activation.
Gorde:
| Argitaratua izan da: | ACS Catal |
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| Egile Nagusiak: | , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2017
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5640319/ https://ncbi.nlm.nih.gov/pubmed/29038742 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b02905 |
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