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Lewis Acid Enabled Copper-Catalyzed Asymmetric Synthesis of Chiral β-Substituted Amides
[Image: see text] Here we report that readily available silyl- and boron-based Lewis acids in combination with chiral copper catalysts are able to overcome the reactivity issues of unactivated enamides, known as the least reactive carboxylic acid derivatives, toward alkylation with organomagnesium r...
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| Gepubliceerd in: | J Am Chem Soc |
|---|---|
| Hoofdauteurs: | , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2017
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5639465/ https://ncbi.nlm.nih.gov/pubmed/28960071 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07344 |
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