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Transition Metal Free C–N Bond Forming Dearomatizations and Aryl C–H Aminations by in Situ Release of a Hydroxylamine-Based Aminating Agent

[Image: see text] We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C–N bond forming dearomatization or aryl C–H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts ac...

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Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Farndon, Joshua J., Ma, Xiaofeng, Bower, John F.
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2017
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5639464/
https://ncbi.nlm.nih.gov/pubmed/28953364
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07830
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