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Transition Metal Free C–N Bond Forming Dearomatizations and Aryl C–H Aminations by in Situ Release of a Hydroxylamine-Based Aminating Agent
[Image: see text] We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C–N bond forming dearomatization or aryl C–H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts ac...
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| 發表在: | J Am Chem Soc |
|---|---|
| Main Authors: | , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
American Chemical
Society
2017
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| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5639464/ https://ncbi.nlm.nih.gov/pubmed/28953364 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07830 |
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