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Dearomatization of electron poor six-membered N-heterocycles through [3 + 2] annulation with aminocyclopropanes

Many abundant and highly bioactive natural alkaloids contain an indolizidine skeleton. A simple, high yielding method to synthesize this scaffold from N-heterocycles was developed. A wide range of pyridines, quinolines and isoquinolines reacted with donor–acceptor (DA)-aminocyclopropanes via an ytte...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Preindl, Johannes, Chakrabarty, Shyamal, Waser, Jérôme
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5637460/
https://ncbi.nlm.nih.gov/pubmed/29147541
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03197a
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