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Dearomatization of electron poor six-membered N-heterocycles through [3 + 2] annulation with aminocyclopropanes

Many abundant and highly bioactive natural alkaloids contain an indolizidine skeleton. A simple, high yielding method to synthesize this scaffold from N-heterocycles was developed. A wide range of pyridines, quinolines and isoquinolines reacted with donor–acceptor (DA)-aminocyclopropanes via an ytte...

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Библиографические подробности
Опубликовано в: :Chem Sci
Главные авторы: Preindl, Johannes, Chakrabarty, Shyamal, Waser, Jérôme
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2017
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5637460/
https://ncbi.nlm.nih.gov/pubmed/29147541
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03197a
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