Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor

The reaction of [(cAAC(Me))BH(3)] (cAAC(Me) = 1-(2,6-(i)Pr(2)C(6)H(3))-3,3,5,5-tetramethylpyrrolidin-2-ylidene) with a range of organolithium compounds led to the exclusive formation of the corresponding (dihydro)organoborates, Li(+)[(cAAC(Me)H)BH(2)R](–) (R = sp(3)-, sp(2)-, or sp-hybridised organi...

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Publicat a:Chem Sci
Autors principals: Auerhammer, Dominic, Arrowsmith, Merle, Braunschweig, Holger, Dewhurst, Rian D., Jiménez-Halla, J. Oscar C., Kupfer, Thomas
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2017
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5637459/
https://ncbi.nlm.nih.gov/pubmed/29147534
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03193a
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