Chargement en cours...
Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor
The reaction of [(cAAC(Me))BH(3)] (cAAC(Me) = 1-(2,6-(i)Pr(2)C(6)H(3))-3,3,5,5-tetramethylpyrrolidin-2-ylidene) with a range of organolithium compounds led to the exclusive formation of the corresponding (dihydro)organoborates, Li(+)[(cAAC(Me)H)BH(2)R](–) (R = sp(3)-, sp(2)-, or sp-hybridised organi...
Enregistré dans:
| Publié dans: | Chem Sci |
|---|---|
| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2017
|
| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5637459/ https://ncbi.nlm.nih.gov/pubmed/29147534 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03193a |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|