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Copper(I)/NO((g)) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO((g)) Disproportionation
A copper complex, [Cu(I)(tmpa)(MeCN)](+), effectively reductively couples NO((g)) at RT in methanol (MeOH), giving a structurally characterized hyponitrito-dicopper( II) adduct. Hydrogen-bonding from MeOH is critical for the hyponitrite complex formation and stabilization. This complex exhibits the...
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| Yayımlandı: | J Am Chem Soc |
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| Asıl Yazarlar: | , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2017
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5630263/ https://ncbi.nlm.nih.gov/pubmed/28820592 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07808 |
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