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Directed Nucleophilic Addition of Phenoxides to Cyclopropenes

Alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically-positioned carboxamide functionality.

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Yamanushkin, Pavel, Lu-Diaz, Michael, Edwards, Andrew, Aksenov, Nicolai A., Rubina, Marina, Rubin, Michael
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5629095/
https://ncbi.nlm.nih.gov/pubmed/28920624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7ob01785e
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