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Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids

How can you use a ruthenium isomerization catalyst twice? A ruthenium-catalyzed sequence for the formal two-carbon scission of allyl groups to carboxylic acids has been developed. The reaction includes an initial isomerization step using commercially available ruthenium catalysts followed by in situ...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Liniger, Marc, Liu, Yiyang, Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5628162/
https://ncbi.nlm.nih.gov/pubmed/28918631
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08496
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