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Nitro-enabled catalytic enantioselective formal umpolung alkenylation of β-ketoesters
A formal umpolung strategy is presented for the enantioselective installation of an alkenyl group with a terminal double bond at a tertiary center. This one-pot two-step sequence relies on the unique features of the nitro group, which after inverting the polarity of the alkenylating agent toward the...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5625255/ https://ncbi.nlm.nih.gov/pubmed/28989696 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02232h |
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