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Total syntheses of both enantiomers of amphirionin 4: A chemoenzymatic based strategy for functionalized tetrahydrofurans

The total syntheses of (−)-amphirionin-4 and (+)-amphirionin-4 have been achieved in a convergent and enantioselective manner. The tetrahydrofuranol cores of amphirionin-4 were constructed in optically active form by enzymatic resolution of racemic cis-3-hydroxy-5-methyldihydrofuran-2(3H)-one. The p...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Ghosh, Arun K., Nyalapatla, Prasanth R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5621746/
https://ncbi.nlm.nih.gov/pubmed/28970641
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2017.02.031
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