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Photoredox ketone catalysis for the direct C–H imidation and acyloxylation of arenes

The photoexcited aryl ketone-catalyzed C–H imidation of arenes and heteroarenes is reported. Using 3,6-dimethoxy-9H-thioxanthen-9-one as a catalyst in combination with a bench-stable imidating reagent, C–N bond formation proceeds with high efficiency and a broad substrate scope. A key part of this m...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Tripathi, Chandra Bhushan, Ohtani, Tsuyoshi, Corbett, Michael T., Ooi, Takashi
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5620997/
https://ncbi.nlm.nih.gov/pubmed/28989599
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01700f
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