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Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)(3) (2–) – a unique entry to aryltricyanoborates

The potassium salt of the boron-centred nucleophile B(CN)(3) (2–) (1) readily reacts with perfluorinated arenes, such as hexafluorobenzene, decafluorobiphenyl, octafluoronaphthalene and pentafluoropyridine, which results in KF and the K(+) salts of the respective borate anions with one {B(CN)(3)} un...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Landmann, Johannes, Hennig, Philipp T., Ignat’ev, Nikolai V., Finze, Maik
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5620525/
https://ncbi.nlm.nih.gov/pubmed/28989626
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02249b
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