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Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl) Borates: A General Synthesis of Chiral Allylboron Reagents

Palladium catalyzed conjunctive cross-coupling is used for the synthesis of enantioenriched allylboron reagents. This reaction employs non-symmetric bis(alkenyl)borates as substrates and appears to occur by a mechanism that involves selective activation of the less substituted alkene, followed by mi...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Edelstein, Emma K., Namirembe, Sheila, Morken, James P.
Format: Artigo
Jezik:Inglês
Izdano: 2017
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5620124/
https://ncbi.nlm.nih.gov/pubmed/28335597
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01774
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