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Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl) Borates: A General Synthesis of Chiral Allylboron Reagents
Palladium catalyzed conjunctive cross-coupling is used for the synthesis of enantioenriched allylboron reagents. This reaction employs non-symmetric bis(alkenyl)borates as substrates and appears to occur by a mechanism that involves selective activation of the less substituted alkene, followed by mi...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5620124/ https://ncbi.nlm.nih.gov/pubmed/28335597 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01774 |
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