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Small endohedral metallofullerenes: exploration of the structure and growth mechanism in the Ti@C(2n) (2n = 26–50) family

The formation of the smallest fullerene, C(28), was recently reported using gas phase experiments combined with high-resolution FT-ICR mass spectrometry. An internally located group IV metal stabilizes the highly strained non-IPR C(28) cage by charge transfer (IPR = isolated pentagon rule). Ti@C(44)...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Mulet-Gas, Marc, Abella, Laura, Dunk, Paul W., Rodríguez-Fortea, Antonio, Kroto, Harold W., Poblet, Josep M.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5590485/
https://ncbi.nlm.nih.gov/pubmed/28936315
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02268h
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