The application of chiroptical spectroscopy (circular dichroism) in quantifying binding events in lanthanide directed synthesis of chiral luminescent self-assembly structures

The binding of asymmetrical and optically pure tridentate ligands (L = 1(S) and 1(R)) containing one carboxylic group and 2-naphthyl as an antenna to lanthanide ions (M = La(iii) and Eu(iii)) was studied in CH(3)CN, showing the successive formation of M:L, M:L(2) and M:L(3) stoichiometric species in...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Kotova, Oxana, Blasco, Salvador, Twamley, Brendan, O'Brien, John, Peacock, Robert D., Kitchen, Jonathan A., Martínez-Calvo, Miguel, Gunnlaugsson, Thorfinnur
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5588118/
https://ncbi.nlm.nih.gov/pubmed/28936303
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02474e
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