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Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes
The one-electron reduction of a cationic (allenylidene)[cyclic(alkyl) (amino)carbene]gold(i) complex leads to the corresponding neutral, paramagnetic, formally gold(0) complex. DFT calculations reveal that the spin density of this highly robust coinage metal complex is mainly located on the allenyli...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5580305/ https://ncbi.nlm.nih.gov/pubmed/28966767 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03654b |
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