Crystalline Diuranium Phosphinidiide and μ‐Phosphido Complexes with Symmetric and Asymmetric UPU Cores

Reaction of [U(Tren(TIPS))(PH(2))] (1, Tren(TIPS)=N(CH(2)CH(2)NSiPr(i) (3))(3)) with C(6)H(5)CH(2)K and [U(Tren(TIPS))(THF)][BPh(4)] (2) afforded a rare diuranium parent phosphinidiide complex [{U(Tren(TIPS))}(2)(μ‐PH)] (3). Treatment of 3 with C(6)H(5)CH(2)K and two equivalents of benzo‐15‐crown‐5...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Rookes, Thomas M., Gardner, Benedict M., Balázs, Gábor, Gregson, Matthew, Tuna, Floriana, Wooles, Ashley J., Scheer, Manfred, Liddle, Stephen T.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5577518/
https://ncbi.nlm.nih.gov/pubmed/28677144
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706002
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