Transition State Gauche Effects Control the Torquoselectivities of the Electrocyclizations of Chiral 1-Azatrienes

Hsung et al. have reported a series of torquoselective electrocyclizations of chiral 1-azahexa-1,3,5-trienes that yield functionalized dihydropyridines. To understand the origins of the torquoselectivities of these azaelectrocyclizations, we modeled these electrocyclic ring closures using the M06-2X...

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Bibliographic Details
Published in:J Org Chem
Main Authors: Patel, Ashay, Vella, Joseph R., Ma, Zhi-Xiong, Hsung, R. P., Houk, K. N.
Format: Artigo
Language:Inglês
Published: 2015
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5555587/
https://ncbi.nlm.nih.gov/pubmed/26435446
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b02085
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