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Regiodivergent Glycosylations of 6-deoxy-Erythronolide B and Ole-andomycin-Derived Macrolactones Enabled by Chiral Acid Catalysis
This work describes the first example of using chiral catalysts to control site-selectivity for the glycosylations of complex polyols such as 6-dEB and oleandomycin-derived macrolactones. The regiodivergent introduction of sugars at the C3, C5 and C11 positions of macrolactones was achieved by selec...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5553906/ https://ncbi.nlm.nih.gov/pubmed/28627172 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03198 |
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