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Regiodivergent Glycosylations of 6-deoxy-Erythronolide B and Ole-andomycin-Derived Macrolactones Enabled by Chiral Acid Catalysis
This work describes the first example of using chiral catalysts to control site-selectivity for the glycosylations of complex polyols such as 6-dEB and oleandomycin-derived macrolactones. The regiodivergent introduction of sugars at the C3, C5 and C11 positions of macrolactones was achieved by selec...
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| Vydáno v: | J Am Chem Soc |
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| Hlavní autoři: | , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2017
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5553906/ https://ncbi.nlm.nih.gov/pubmed/28627172 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03198 |
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