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A Stable Anionic Dithiolene Radical
Sulfurization of anionic N-heterocyclic dicarbene, [:C{[N(2,6-Pr(i)(2)C(6)H(3))](2)CHCLi}](n) (2), with elemental sulfur (in a 1:2 ratio) in Et(2)O at low temperature gives 3 by inserting two sulfur atoms into the Li–C (i.e., C2 and C4) bonds in polymeric 2. Further reaction of 3 with 2 equiv of ele...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2017
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5551979/ https://ncbi.nlm.nih.gov/pubmed/28482154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03794 |
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