A Stable Anionic Dithiolene Radical

Sulfurization of anionic N-heterocyclic dicarbene, [:C{[N(2,6-Pr(i)(2)C(6)H(3))](2)CHCLi}](n) (2), with elemental sulfur (in a 1:2 ratio) in Et(2)O at low temperature gives 3 by inserting two sulfur atoms into the Li–C (i.e., C2 and C4) bonds in polymeric 2. Further reaction of 3 with 2 equiv of ele...

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Publicat a:J Am Chem Soc
Autors principals: Wang, Yuzhong, Hickox, Hunter P., Xie, Yaoming, Wei, Pingrong, Blair, Soshawn A., Johnson, Michael K., Schaefer, Henry F., Robinson, Gregory H.
Format: Artigo
Idioma:Inglês
Publicat: 2017
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5551979/
https://ncbi.nlm.nih.gov/pubmed/28482154
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03794
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