Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: an Experimental and Computational Study

Cp(X)Rh(III)-catalyzed C-H functionalization reactions are a proven method for the efficient assembly of small molecules. However, rationalization of the effects of cyclopentadienyl (Cp(X)) ligand structure on reaction rate and selectivity has been viewed as a black box, and a truly systematic study...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Piou, Tiffany, Romanov-Michailidis, Fedor, Romanova-Michaelides, Maria, Jackson, Kelvin E., Semakul, Natthawat, Taggart, Trevor D., Newell, Brian S., Rithner, Christopher D., Paton, Robert S., Rovis, Tomislav
Médium: Artigo
Jazyk:Inglês
Vydáno: 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5545783/
https://ncbi.nlm.nih.gov/pubmed/28060499
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11670
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