Confining the spin between two metal atoms within the carbon cage: redox-active metal–metal bonds in dimetallofullerenes and their stable cation radicals†

Lanthanide–lanthanide bonds are exceptionally rare, and dimetallofullerenes provide a unique possibility to stabilize and study these unusual bonding patterns. The presence of metal–metal bonds and consequences thereof for the electronic properties of M(2)@C(82) (M = Sc, Er, Lu) are addressed by ele...

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Publicat a:Nanoscale
Autors principals: Samoylova, Nataliya A., Avdoshenko, Stanislav M., Krylov, Denis S., Thompson, Hannah R., Kirkhorn, Amelia C., Rosenkranz, Marco, Schiemenz, Sandra, Ziegs, Frank, Wolter, Anja U. B., Yang, Shangfeng, Stevenson, Steven, Popov, Alexey A.
Format: Artigo
Idioma:Inglês
Publicat: 2017
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5544111/
https://ncbi.nlm.nih.gov/pubmed/28574078
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7nr02288c
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