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Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates
Nickel-catalyzed enantioselective cross- couplings between symmetric cyclic sulfates and aromatic Grignard reagents are described. These reactions are effective with a broad range of substituted cyclic sulfates and deliver products with asymmetric tertiary carbon centers. Mechanistic experiments poi...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5539537/ https://ncbi.nlm.nih.gov/pubmed/27276235 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03384 |
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