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An Iron(II) Hydride Complex of a Ligand with two Adjacent β-Diketiminate Binding sites and its Reactivity
After lithiation of PYR-H(2) (PYR = [(HCCMeNC(6)H(3)(iPr)(2))(2)(C(5)H(5)-N)](2−)) – the precursor of an expanded β-diketiminato ligand system with two binding pockets – with KN(TMS)2 the reaction of the resulting potassium salt with FeBr(2) led to a dinuclear iron(II) bromide complex [(PYR)Fe(μ-Br)...
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| Veröffentlicht in: | Dalton Trans |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5536248/ https://ncbi.nlm.nih.gov/pubmed/26757878 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5dt04266f |
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