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An Iron(II) Hydride Complex of a Ligand with two Adjacent β-Diketiminate Binding sites and its Reactivity

After lithiation of PYR-H(2) (PYR = [(HCCMeNC(6)H(3)(iPr)(2))(2)(C(5)H(5)-N)](2−)) – the precursor of an expanded β-diketiminato ligand system with two binding pockets – with KN(TMS)2 the reaction of the resulting potassium salt with FeBr(2) led to a dinuclear iron(II) bromide complex [(PYR)Fe(μ-Br)...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Gehring, Henrike, Metzinger, Ramona, Braun, Beatrice, Herwig, Christian, Harder, Sjoerd, Ray, Kallol, Limberg, Christian
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5536248/
https://ncbi.nlm.nih.gov/pubmed/26757878
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5dt04266f
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